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Creator:	Zdravković, Aleksandar 1987-
Title:	Sinteza, karakterizacija i primena hidrogelova na bazi N-izopropilakrilamida i anjonskih komonomera za uklanjanje hroma, mangana i olova iz vodenih rastvora
Copyright date:	2019
Permanent link:	https://phaidrani.ni.ac.rs/detail_object/o:1606?tab=0#mda
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Select license:	Autorstvo-Nekomercijalno-Bez prerade 3.0 Srbija (CC BY-NC-ND 3.0)
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Academic metadata

Theses Type:	Doktorska disertacija
Academic Expertise :	Tehničko-tehnološke nauke
University:	Univerzitet u Nišu
Faculty:	Tehnološki fakultet
Group:	Katedra za hemijske nauke

Other Theses Metadata

Alternative title:	Synthesis, characterization and application of hydrogels based on N-isopropylacrylamide and anionic comonomers for chromium, manganese and lead removal from aqueous solutions
Publisher:	[A. S. Zdravković]
Format:	[12], 149 listova
description:	Biografija autora: list 139; Bibliografija: listovi 140-146.
description:	Datum odbrane: 24.09.2019.
description:	Chemistry and chemical technology
Other responsibilities:	Nikolić, Ljubiša 1963- (mentor)
Other responsibilities:	Džunuzović, Enis 1971- (član komisije)
Other responsibilities:	Cakić, Suzana 1967- (predsednik komisije)
Other responsibilities:	Nikolić, Vesna 1965- (član komisije)
Abstract:	In this doctoral dissertation, the hydrogels sensitive to temperature and pH changes based on N-isopropylacrylamide (NIPAM) and anionic comonomers (acrylic acid, AA, and methacrylic acid, MAA) were synthesized and investigated as adsorbent materials for removal of Cr(VI), Mn(II) and Pb(II) ions from aqueous solutions. The hydrogels were synthesized by radical polymerization process by varying the content of comonomer and crosslinker. The obtained poly(Nisopropylacrylamide- co-acrylic acid) (p(NIPAM/AA)) and poly(Nisopropylacrylamide- co-methacrylic acid) (p(NIPAM/MAA)) hydrogels were characterized using the following methods: Fourier transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM), X-ray diffraction (XRD), high pressure liquid chromatography (HPLC) and determining the swelling intensity in aqueous solutions of different temperatures and pH values. Kinetics of hydrogel swelling before and after the lyophilization process, as well as swelling reversibility through 3 alternate swell-shrink cycles under the influence of temperature were investigated. A full three-level experimental design was applied in order to describe the swelling of synthesized hydrogels as a function of temperature, pH value and crosslinker content by a mathematical model. Characterization of p(NIPAM/AA) and p(NIPAM/MAA) hydrogels with adsorbed metal ions was performed by FTIR and SEM method. Heavy metal ions in the structure of hydrogels were identified by energydispersive X-ray spectroscopy (EDX). The influence of pH, temperature, contact time and initial concentration of heavy metals on adsorption capacity of hydrogels was investigated. The kinetic and equilibrium data match best to the pseudo-second order model and Langmuir adsorption isotherm. Based on the thermodynamic results, it has been concluded that the adsorption of Cr(VI), Mn(II) and Pb(II) ions from aqueous solutions onto hydrogels was spontaneous and exothermic process. The adsorption capacity of p(NIPAM/AA) and p(NIPAM/MAA) hydrogels for investigated metal ions decreases in the following order: Pb(II)>Cr(VI)>Mn(II). Hydrogels based on NIPAM and AA or MAA are considered to be suitable adsorbents for removal of Cr(VI), Mn(II) and Pb(II) ions from aqueous solutions, due to high efficiency in the temperature range from 25 to 45 °C.
Authors Key words:	hidrogel, bubrenje, difuzija, adsorpcija, teški metal, kinetika
Authors Key words:	hydrogel, swelling, diffusion, adsorption, heavy metal, kinetics
Classification:	544.773.432:66.095.26]:502/504(043.3)
Subject:	T 390
Language:	Serbian
Identifier:	534136470
Type:	Tekst

Abstract:

In this doctoral dissertation, the hydrogels sensitive to temperature and pH changes based on N-isopropylacrylamide (NIPAM) and anionic comonomers (acrylic acid, AA, and methacrylic acid, MAA) were synthesized and investigated as adsorbent materials for removal of Cr(VI), Mn(II) and Pb(II) ions from aqueous solutions. The hydrogels were synthesized by radical polymerization process by varying the content of comonomer and crosslinker. The obtained poly(Nisopropylacrylamide- co-acrylic acid) (p(NIPAM/AA)) and poly(Nisopropylacrylamide- co-methacrylic acid) (p(NIPAM/MAA)) hydrogels were characterized using the following methods: Fourier transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM), X-ray diffraction (XRD), high pressure liquid chromatography (HPLC) and determining the swelling intensity in aqueous solutions of different temperatures and pH values. Kinetics of hydrogel swelling before and after the lyophilization process, as well as swelling reversibility through 3 alternate swell-shrink cycles under the influence of temperature were investigated. A full three-level experimental design was applied in order to describe the swelling of synthesized hydrogels as a function of temperature, pH value and crosslinker content by a mathematical model. Characterization of p(NIPAM/AA) and p(NIPAM/MAA) hydrogels with adsorbed metal ions was performed by FTIR and SEM method. Heavy metal ions in the structure of hydrogels were identified by energydispersive X-ray spectroscopy (EDX). The influence of pH, temperature, contact time and initial concentration of heavy metals on adsorption capacity of hydrogels was investigated. The kinetic and equilibrium data match best to the pseudo-second order model and Langmuir adsorption isotherm. Based on the thermodynamic results, it has been concluded that the adsorption of Cr(VI), Mn(II) and Pb(II) ions from aqueous solutions onto hydrogels was spontaneous and exothermic process. The adsorption capacity of p(NIPAM/AA) and p(NIPAM/MAA) hydrogels for investigated metal ions decreases in the following order: Pb(II)>Cr(VI)>Mn(II). Hydrogels based on NIPAM and AA or MAA are considered to be suitable adsorbents for removal of Cr(VI), Mn(II) and Pb(II) ions from aqueous solutions, due to high efficiency in the temperature range from 25 to 45 °C.